Proton-Catalyzed Decomposition of α-Hydroxyalkyl-Hydroperoxides in Water
نویسندگان
چکیده
منابع مشابه
Role of tunable acid catalysis in decomposition of α-hydroxyalkyl hydroperoxides and mechanistic implications for tropospheric chemistry.
Electronic structure calculations have been used to investigate possible gas-phase decomposition pathways of α-hydroxyalkyl hydroperoxides (HHPs), an important source of tropospheric hydrogen peroxide and carbonyl compounds. The uncatalyzed as well as water- and acid-catalyzed decomposition of multiple HHPs have been examined at the M06-2X/aug-cc-pVTZ level of theory. The calculations indicate ...
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ژورنال
عنوان ژورنال: Environmental Science & Technology
سال: 2020
ISSN: 0013-936X,1520-5851
DOI: 10.1021/acs.est.0c03438